Organic Chemistry Frontiers · 2024 · 25 citations · 107 references
Natural SciencesChemical EngineeringChemistryCatalysisOrganic ChemistryCross-coupling ReactionsOrganic SynthesisPhotocatalysisPhotochemical SynthesisPhotochemistryReaction MechanismsAlkyne Coupling ReactionsKetonesPhotoredox CatalysisPhotoredox Cross-couplingReactivity
NHC and photocatalysis dual-catalyzed mono/difluoromethylative acylation of 1,3-enynes was realized, providing fluormethyl-substituted allenyl ketones. SO 2 might play a critical role in achieving high reactivity and selectivity.
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An overview of N-heterocyclic carbenes
Matthew N. Hopkinson, Christian Richter, Michael Schedler et al. · Nature · 2014 · 4.2K citations
Practical and innate carbon–hydrogen functionalization of heterocycles
Yuta Fujiwara, Janice A. Dixon, Fionn O’Hara et al. · Nature · 2012 · 924 citations · Full text