Stable mass-selected AuTiO_<i>x</i> nanoparticles for CO oxidation

Abstract

Stability under reactive conditions poses a common challenge for cluster- and nanoparticle-based catalysts. Since the catalytic properties of <5 nm gold nanoparticles were first uncovered, optimizing their stability at elevated temperatures for CO oxidation has been a central theme. Here we report direct observations of improved stability of AuTiO_<i>x</i> alloy nanoparticles for CO oxidation compared with pure Au nanoparticles on TiO₂. The nanoparticles were synthesized using a magnetron sputtering, gas-phase aggregation cluster source, size-selected using a lateral time-of-flight mass filter and deposited onto TiO₂-coated micro-reactors for thermocatalytic activity measurements of CO oxidation. The AuTiO_<i>x</i> nanoparticles exhibited improved stability at elevated temperatures, which is attributed to a self-anchoring interaction with the TiO₂ substrate. The structure of the AuTiO_<i>x</i> nanoparticles was also investigated in detail using ion scattering spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. The measurements showed that the alloyed nanoparticles exhibited a core-shell structure with an Au core surrounded by an AuTiO_<i>x</i> shell. The structure of these alloy nanoparticles appeared stable even at temperatures up to 320 °C under reactive conditions, for more than 140 hours. The work presented confirms the possibility of tuning catalytic activity and stability <i>via</i> nanoparticle alloying and self-anchoring on TiO₂ substrates, and highlights the importance of complementary characterization techniques to investigate and optimize nanoparticle catalyst designs of this nature.