Experimental investigation on combustion and emission characteristics of non-premixed ammonia/hydrogen flame

Abstract

The use of ammonia and hydrogen as fuels to decarbonise the heavy transport industry has attracted worldwide attention. In this work, a swirl-enhanced combustion test rig has been built to investigate the combustion and emission characteristics of non-premixed ammonia/hydrogen flames. The blowoff limits were first examined to ensure that a range of stable flames could be achieved. Emissions containing nitric oxide (NO), nitrous oxide (NO2), ammonia slip (NH3) and unburnt hydrogen (H2) were then measured with a variety of global equivalence ratios, hydrogen blending ratios, inlet gas temperature, swirl numbers and combustion chamber insulation conditions. The structure of non-premixed ammonia/hydrogen flames and the relationship between excited hydroxyl radicals (OH*) and NO emission were revealed using OH* chemiluminescence profiles. The stable non-premixed ammonia/hydrogen flames were achieved when the hydrogen blending ratio was greater than 20%. The optimal emission performance was achieved under stoichiometric conditions, as determined by combustion efficiency. The insulation conditions of the combustor wall played a key role in the emission results, as significant growth of NO and NO2 as well as a reduction of ammonia slip were found. Although a lower swirl number improved the flame stability range, the increases in NO and NO2 emissions were observed.