Upconversion Luminescence Properties of Pr³⁺-Doped BaYF₅ Nanoparticles Prepared by Microwave Hydrothermal Method

Abstract

Pure and Pr³⁺-doped BaYF₅ nanoparticles were synthesized by the microwave hydrothermal method. The nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and optical spectroscopy. The XRD and TEM confirm that the average size of nanoparticles is in the range of 26-37 nm. The optical excitation and luminescence spectra of BaYF₅:Pr³⁺ nanoparticles are presented in the visible and ultraviolet (UV) range. It has been verified that Pr³⁺ ions are capable of emitting UV-C photons when excited by a 444 nm laser. This emission arises from a two-photon energy-transfer upconversion mechanism. The concentration dependence of the upconversion luminescence of BaYF₅:Pr³⁺ was studied.