Ultrafast and persistent photoinduced phase transition at room temperature monitored by streaming powder diffraction

Abstract

Abstract Ultrafast photoinduced phase transitions at room temperature, driven by a single laser shot and persisting long after stimuli, represent emerging routes for ultrafast control over materials’ properties. Time-resolved studies provide fundamental mechanistic insight into far-from-equilibrium electronic and structural dynamics. Here we study the photoinduced phase transformation of the Rb 0.94 Mn 0.94 Co 0.06 [Fe(CN) 6 ] 0.98 material, designed to exhibit a 75 K wide thermal hysteresis around room temperature between Mn III Fe II tetragonal and Mn II Fe III cubic phases. We developed a specific powder sample streaming technique to monitor by ultrafast X-ray diffraction the structural and symmetry changes. We show that the photoinduced polarons expand the lattice, while the tetragonal-to-cubic photoinduced phase transition occurs within 100 ps above threshold fluence. These results are rationalized within the framework of the Landau theory of phase transition as an elastically-driven and cooperative process. We foresee broad applications of the streaming powder technique to study non-reversible and ultrafast dynamics.