Pressure‐Induced Remarkable Spectral Red‐Shift in Mn²⁺‐Activated NaY₉(SiO₄)₆O₂ Red‐Emitting Phosphors for High‐Sensitive Optical Manometry

Abstract

To settle the low sensitivity of luminescent manometers, the Mn²⁺ -activated NaY₉ (SiO₄ )₆ O₂ red-emitting phosphors with splendid pressure sensing performances are developed. Excited by 408 nm, the resulting products emit bright red emission originating from ⁴ T₁ (⁴ G) → ⁶ A₁ transition of Mn²⁺ , in which the optimal concentration of the activator ion is ≈1 mol%. Moreover, the admirable thermal stability of the developed phosphors is studied and confirmed by the temperature-dependent emission spectra, based on which the activation energy is derived to be 0.275 eV. By analyzing the pressure-dependent Raman spectra, the structural stability of the synthesized compounds at extreme conditions is verified. Furthermore, the designed phosphors exhibit remarkable spectral red-shift at elevated pressure. Especially, as pressure increases from 0.75 to 7.16 GPa, the emission band centroid shifts from 617.2 to 663.4 nm, resulting in a high sensitivity (dλ/dP) of 7.00 nm GPa^-1 , whereas the full width at half maximum (FWHM) increases from 83.0 to 110.6 nm, leading to the ultra-high sensitivity (dFWHM/dP) of 10.13 nm GPa^-1 . These achievements manifest that the designed red-emitting phosphors are appropriate for ultrasensitive optical manometry. More importantly, the developed manometer is a current global leader in sensitivity, when operating in the band-width mode, that is, FWHM.