Concepedia

The rigidity and chelation effect of ligands on the hydrogen evolution reaction catalyzed by Ni(<scp>ii</scp>) complexes

Anjali Mishra, Gaurav K. Mishra, Anamika Anamika, Nanhai Singh, Rama Kant, Kamlesh Kumar

Dalton Transactions · 2023 · 19 citations · 70 references

DOI

Concepts

Abstract

Heteroleptic Ni( ii ) dithiolate complexes containing phosphine ligands are investigated as electrocatalyst for proton reduction. This study highlights the effect of rigidity and chelation properties of phosphine ligands on electrocatalytic activity.

References

70

Inorganic electronic spectroscopy

Gopala Krishna Murthy H R · Journal of Molecular Structure · 1985 · 5.9K citations

Structural variation in copper(<scp>i</scp>) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ<sub>4</sub>

Lei Yang, Douglas R. Powell, Robert P. Houser · Dalton Transactions · 2007 · 3.4K citations

, , +14

Infrared and Raman Spectra of Inorganic and Coordination Compounds

Kenneth R. Seddon · Journal of Organometallic Chemistry · 1987 · 3.4K citations

, , +14

Nickel-Based Electrocatalysts for Energy-Related Applications: Oxygen Reduction, Oxygen Evolution, and Hydrogen Evolution Reactions

Varun Vij, Siraj Sultan, Ahmad M. Harzandi et al. · ACS Catalysis · 2017 · 1.2K citations

, , +17

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s <sup>−1</sup> for H <sub>2</sub> Production

Monte L. Helm, Michael Stewart, R. Morris Bullock et al. · Science · 2011 · 1.2K citations · Full text

, , +17