Confinement of <i>p</i>‐Xylene in the Pores of a Bilanthanide Metal–Organic Framework for Highly Selective Recognition

Abstract

The rapid and accurate sensing of p-xylene, an essential raw material with a multi-billion-dollar market, in xylene mixture is of great significance in industry; however, the highly similar molecular structures, energy levels, and spectral characteristics of xylene isomers make the selective recognition extremely challenging. Metal-organic frameworks (MOFs) exhibiting tailorable pores and potential binding sites provide prospects for xylene sensing but a comprehensive understanding of the pore effect is still elusive, primarily due to the intricacies involved in the sensing process. Herein, we reported a robust bilanthanide MOF NKU-999-EuTb with precisely engineered pores to accommodate p-xylene, of which the binding sites were confirmed by single crystal X-ray diffraction and dynamic magnetic susceptibilities. NKU-999-EuTb exhibits high-performance in selective recognition for p-xylene towards its isomers. Through a systematical study, it was revealed that absorbing p-xylene into the pores governs the sensing performance. This work provides insights for developing advanced sensing materials for complex isomers.