National Science Review · 2023 · 74 citations · 76 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsMaterials PhysicsSolid State PhysicsElectron-phonon InteractionsHigh-pressure ThermodynamicsHigh-temperature MaterialsPhase TransitionsStrongly Correlated Electron SystemsSuperconducting MaterialsExperimental StudiesHigh-temperature SuperconductivityHigh-temperature SuperconductorsPhonon-mediated SuperconductivityStructural StabilitySuperconducting Critical TemperatureTransition State Structure
ABSTRACT Since the discovery of the high-temperature superconductors H3S and LaH10 under high pressure, compressed hydrides have received extensive attention as promising candidates for room-temperature superconductors. As a result of current high-pressure theoretical and experimental studies, it is now known that almost all the binary hydrides with a high superconducting transition temperature (Tc) require extremely high pressure to remain stable, hindering any practical application. In order to further lower the stable pressure and improve superconductivity, researchers have started exploring ternary hydrides and had many achievements in recent years. Here, we discuss recent progress in ternary hydrides, aiming to deepen the understanding of the key factors regulating the structural stability and superconductivity of ternary hydrides, such as structural motifs, bonding features, electronic structures, electron–phonon coupling, etc. Furthermore, the current issues and challenges of superconducting ternary hydrides are presented, together with the prospects and opportunities for future research.
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