Concepedia

Direct air-induced arylphosphinoyl radicals for the synthesis of benzo[<i>b</i>]phosphole oxides

Mingqing Huang, Haiyang Huang, Mengyao You, Xinxin Zhang, Longgen Sun, Chao Chen, Zhichao Mei, Ruchun Yang, Qiang Xiao

Green Chemistry · 2023 · 17 citations · 44 references

DOI

Concepts

Abstract

The direct air-oxidation strategy enables the transformation of arylphosphine oxides into phosphinoyl radicals, which are subsequently used in the synthesis of benzo[ b ]phosphole oxides by combining with various alkynes.

References

44

Metal-Free, Visible Light-Photocatalyzed Synthesis of Benzo[<i>b</i>]phosphole Oxides: Synthetic and Mechanistic Investigations

Valentin Quint, Fabrice Morlet‐Savary, Jean‐François Lohier et al. · Journal of the American Chemical Society · 2016 · 337 citations

, , +16

Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[<i>b</i>]phosphole Oxides

Yunrong Chen, Wei‐Liang Duan · Journal of the American Chemical Society · 2013 · 293 citations

, , +10

Toward Functional π-Conjugated Organophosphorus Materials:  Design of Phosphole-Based Oligomers for Electroluminescent Devices

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Phosphonium‐ and Borate‐Bridged Zwitterionic Ladder Stilbene and Its Extended Analogues

Aiko Fukazawa, Hiroshi Yamada, Shigehiro Yamaguchi · Angewandte Chemie International Edition · 2008 · 222 citations

, , +4

An Approach to Benzophosphole Oxides through Silver‐ or Manganese‐Mediated Dehydrogenative Annulation Involving CC and CP Bond Formation

Yuto Unoh, Koji Hirano, Tetsuya Satoh et al. · Angewandte Chemie International Edition · 2013 · 219 citations

, , +6