High-Temperature corrosion of P91/T91, 304L, Sanicro 28 and Inconel 625 exposed at 600 °C under continuous KCl deposition

Abstract

This study investigates the corrosion attack after breakaway oxidation on four commercial alloys (T91/P91, 304L, Sanicro 28 and Inconel 625) in the presence of KCl(g)/KCl(s) at 600 °C. The study suggests that an increase in corrosion resistant alloying elements (mainly nickel and chromium) results in the decrease of the thickness of the general oxide scale and not equally deep alloy grain boundary attack for the austenitic alloys. The corrosion attack in the presence of KCl is suggested to proceed by chromate formation and chlorine-induced acceleration of the diffusion of ions through the scale.