A Heterometallic Porphyrin Dimer as a Potential Quantum Gate: Magneto‐Structural Correlations and Spin Coherence Properties

Abstract

Abstract In the development of two‐qubit quantum gates, precise control over the intramolecular spin‐spin interaction between molecular spin units plays a pivotal role. A weak but measurable exchange coupling is especially important for achieving selective spin addressability that allows controlled manipulation of the computational basis states |00⟩ |01⟩ |10⟩ |11⟩ by microwave pulses. Here, we report the synthesis and Electron Paramagnetic Resonance (EPR) study of a heterometallic meso‐meso (m‐m) singly‐linked V IV O−Cu II porphyrin dimer. X‐band continuous wave EPR measurements in frozen solutions suggest a ferromagnetic exchange coupling of ca. 8 ⋅ 10 −3 cm −1 . This estimation is supported by Density Functional Theory calculations, which also allow disentangling the ferro‐ and antiferromagnetic contributions to the exchange. Pulsed EPR experiments show that the dimer maintains relaxation times similar to the monometallic Cu II porphyrins. The addressability of the two individual spins is made possible by the different g ‐tensors of V IV and Cu II ‐ions, in contrast to homometallic dimers where tilting of the porphyrin planes plays a key role. Therefore, single‐spin addressability in the heterometallic dimer can be maintained even with small tilting angles, as expected when deposited on surface, unlocking the full potential of molecular quantum gates for practical applications.