Hydroxyfluorooxoborate (NH₄)[C(NH₂)₃][B₃O₃F₄(OH)] for exploring the effects of cation substitution on structure and optical properties

Abstract

Cation substitution is a straightforward but effective technique for improving the structure and properties; however, controlling directed substitution still poses significant difficulties. Herein, a metal-free hydroxyfluorooxoborate (NH₄)[C(NH₂)₃][B₃O₃F₄(OH)] has been synthesized using the strategy of heterologous substitution based on the template of A₂[B₃O₃F₄(OH)]. Tunable structure and optical properties have been achieved <i>via</i> varied A-site cation substitution. The intrinsic mechanism for this tunability was established by crystallography and theoretical research.