Unprecedented Multifunctionality in Novel Monophase Micro/Nanostructured Ti‐Zn Alloy

Hajeesh Kumar Vikraman, Jeena George, Rence P. Reji, Guru Prasad Kuppuswamy, Sanjay D. Sutar, Anita Swami, Sharmiladevi Ramamoorthy, Anandhakumar Sundaramurthy, Sumit Pramanik, Surya Velappa Jayaraman,

Small · 2023 · 10 citations · 69 references

Concepts

Abstract

Abstract It is always challenging to integrate multiple functions into one material system. However, those materials/devices will address society's critical global challenges and technological demands if achieved with innovative design strategies and engineering. Here, one such material with a broader spectrum of desired properties appropriate for seven applications is identified and explored, and a glucose‐sensing‐triggered energy‐storage mechanism is demonstrated. To date, the Titanium (Ti)‐Zinc (Zn) binary alloys are investigated only as mixed phases and for a maximum of three applications. In contrast, the novel single phase of structurally stable 50 Ti‐50 Zn (Ti 0.5 Zn 0.5 ) is synthesized and proven suitable for seven emerging applications. Interestingly, it is thermally stable up to 750 °C and possesses excellent mechanical, tribological properties and corrosion resistance. While exceptional biocompatibility is evident even up to a concentration of 500 µg mL −1 , the antibacterial activity against E. coli is also seen. Further, rapid detection and superior selectivity for glucose, along with supercabattery behavior, unambiguously demonstrate that this novel monophase is a remarkable multifunctional material than the existing mixed‐phase Ti‐Zn compounds. The coin‐cell supercapacitor shows outstanding stability up to 30 000 cycles with >100% retention capacity. This allows us to prototype a glucose‐sensing‐triggered energy‐storage‐device system for wearable point‐of‐care diagnostic applications.

References

69