Transfer-Printing Hydrogel-Based Platform for Moisture-Driven Dynamic Display and Optical Anti-Counterfeiting

Abstract

Humidity-responsive materials offer a promising approach to achieving tunable metasurface systems due to their fast and reversible swelling responses to moisture, which enables many important applications, such as real-time humidity sensing, optical switches, dynamic displays, and optical information encryption. However, the humidity-responsive structural coloration generally cannot provide a high spatial resolution and requires a complex patterning process. Here, we present a scalable moisture-driven color-changing Fabry-Pérot (FP)-like cavity composed of a polyvinyl alcohol layer sandwiched between an upper gold nanoparticles assembly and a bottom gold mirror. Through nanoparticle contact printing, we pixelated these cavities with sub-micrometer sizes without crosstalk and achieved an ultrahigh display resolution of ∼400 nm. Meanwhile, these nanoparticle-based FP (NBFP) cavities exhibit more vibrant colors than those of conventional film-based ones due to broadband absorption of the disordered nanoparticle assembly. Moreover, the NBFP cavities exhibit a rapid response (<300 ms), benefiting from the membrane pores formed in the gaps between the adjacent nanoparticles. Finally, we demonstrated the applications of the NBFP cavities in optical anti-counterfeiting and dynamic multi-color printing. These results suggest that our approach will help to realize a colorful, fast, and ultrahigh-resolution dynamic display device in optical security and colorimetric sensing.