Organic Chemistry Frontiers · 2023 · 15 citations · 51 references
We herein report an efficient one-pot strategy for the stereodivergent asymmetric synthesis of various P-atropisomeric Si-stereogenic monohydrosilanes with excellent stereoselectivity from dichlorosilanes.
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Berry pseudorotation and turnstile rotation
Ivar Ugi, Dieter Marquarding, Hans Klusacek et al. · Accounts of Chemical Research · 1971 · 309 citations
Hendrik F. T. Klare, Martin Oestreich · Dalton Transactions · 2010 · 205 citations
Molecular Sieve, Inorganic Chemistry, Known Silylium Ions +12
Silicon-Stereogenic Silanes in Asymmetric Catalysis
Martin Oestreich · Synlett · 2007 · 189 citations
Chemical Engineering, Enantioselective Synthesis, Engineering +10