Concepedia

MnBr(CO)<sub>5</sub>: a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

Anthony Vivien, Laurent Veyre, Raphaël Mirgalet, Clément Camp, Chloé Thieuleux

Green Chemistry · 2023 · 12 citations · 31 references

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Abstract

Commercially available MnBr(CO) 5 was found to be a remarkable catalyst for olefin hydrosilylation reactions using a wide range of olefins and silanes. This system tolerates unpurified substrates and can be used in green solvents under ambient air.

References

31

CHEM21 selection guide of classical- and less classical-solvents

Denis Prat, A.S. Wells, John Hayler et al. · Green Chemistry · 2015 · 2.1K citations · Full text

, , +10

The E factor 25 years on: the rise of green chemistry and sustainability

Roger A. Sheldon · Green Chemistry · 2016 · 1.4K citations

, , +9

Organosilicon Molecules with Medicinal Applications

Annaliese K. Franz, Sean O. Wilson · Journal of Medicinal Chemistry · 2012 · 1.1K citations · Full text

, , +17

Updating and further expanding GSK's solvent sustainability guide

Catherine M. Alder, John Hayler, Richard K. Henderson et al. · Green Chemistry · 2016 · 1K citations

, , +7

Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation

Suzanne C. Bart, Emil B. Lobkovsky, Paul J. Chirik · Journal of the American Chemical Society · 2004 · 818 citations

, , +16