Coupled electrochemical–mechanical model for fracture analysis in active materials of lithium ion batteries

Abstract

Mechanical degradation is a significant cause of battery aging: the stress arising in the electrode microstructure during operation causes fractures, leading to capacity and power fade. This work aims to quantify the fracture behavior of LCO-graphite battery by computing the stress intensity factor. At first, the full electrochemistry of the cell is modeled to obtain realistic boundary conditions for the fracture model linked to user-defined battery usage. The fracture model of a spherical active material particle is implemented in Ansys to compute stress intensity factor with modified J-integral for mechanical-diffusive phenomena. Three aspects are deepened: (a) The effects of the mechanical-diffusive coupling at the crack tip, and its influence on the stress intensity factor; (b) Assessing fracture propagation due to static loading and its stability; (c) Creating a fracture diagram which quantifies the level of fracture due to the combination of different operating conditions and geometry of the electrode microstructure. Results show that crack propagation in a single cycle is limited to high current, but it is likely to be unstable. Furthermore, it is quantified how greater current and particle radius increase the stress intensity factor, aiming to provide electrode design advice in the perspective of increasing battery life.