International Journal of Electrochemical Science · 2013 · 99 citations · 45 references
Natural SciencesMaterials EngineeringMaterials ScienceCorrosion ScienceMetallurgySurface ScienceCorrosion InhibitorsCorrosion KineticsCorrosion MechanismsCorrosion Of SteelsCorrosion ThermodynamicsCorrosion-resistant MaterialsActivation EnergyAdsorption PhenomenaCorrosion InhibitionCorrosion Inhibition MechanismsCorrosion Inhibitors For Mild SteelGravimetric MeasurementLangmuir Adsorption ModelTemperature Effects On Inhibitor Performance
The corrosion inhibition mechanism of the Curcuma longa extract on mild steel surface in 1 M HCl has been studied at different temperatures (30-55 o C) by gravimetric measurements. The inhibition efficiency decreases with increasing temperature. As the concentration of the extract increased, higher activation energy, enthalphy of activation and entropy of activation were obtained. The inhibition were physisorption in nature with an endothermic reaction. The adsorption process was more favoured at lower temperatures with larger negative standard free energy. The adsorption process on the mild steel surface obeys the Langmuir adsorption isotherm.
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Ehteram A. Noor, Aisha H. Al‐Moubaraki · Materials Chemistry and Physics · 2008 · 629 citations
Natural Sciences, Materials Engineering, Materials Science +17