Synthesis and Evaluation of Interfacial Properties and Carbon Capture Capacities of the Imidazolium-Based Ionic Liquid Surfactant

Abstract

Ionic liquid as a chemical flooding agent has broad application prospect in enhancing oil recovery. In this study, a bifunctional imidazolium-based ionic liquid surfactant was synthesized, and its surface-active, emulsification capacity, and CO₂ capture performance were investigated. The results show that the synthesized ionic liquid surfactant combines the characteristics of reducing interfacial tension, emulsification, and CO₂ capture. The IFT values for [C₁₂mim][Br], [C₁₄mim][Br], and [C₁₆mim][Br] could decrease from 32.74 mN/m to 3.17, 0.54, and 0.051 mN/m, respectively, with increasing concentration. In addition, the emulsification index values are 0.597 for [C₁₆mim][Br], 0.48 for [C₁₄mim][Br], and 0.259 for [C₁₂mim][Br]. The surface-active and emulsification capacity of ionic liquid surfactants improved with the increase in alkyl chain length. Furthermore, the absorption capacities reach 0.48 mol CO₂ per mol of ionic liquid surfactant at 0.1 MPa and 25 °C. This work provides theoretical support for further CCUS-EOR research and the application of ionic liquid surfactants.