Enhancing Cu2+ Ion Removal: An Innovative Approach Utilizing Modified Frankincense Gum Combined with Multiwalled Carbon Tubes and Iron Oxide Nanoparticles as Adsorbent

Abstract

Aquatic pollution, which includes organic debris and heavy metals, is a severe issue for living things. Copper pollution is hazardous to people, and there is a need to develop effective methods for eliminating it from the environment. To address this issue, a novel adsorbent composed of frankincense-modified multi-walled carbon nanotubes (Fr-MMWCNTs) and Fe₃O₄ [Fr-MWCNT-Fe₃O₄] was created and subjected to characterization. Batch adsorption tests showed that Fr-MWCNT-Fe₃O₄ had a maximum adsorption capacity of 250 mg/g at 308 K and could efficiently remove Cu²⁺ ions over a pH range of 6 to 8. The adsorption process followed the pseudo-second-order and Langmuir models, and its thermodynamics were identified as endothermic. Functional groups on the surface of modified MWCNTs improved their adsorption capacity, and a rise in temperature increased the adsorption efficiency. These results highlight the Fr-MWCNT-Fe₃O₄ composites' potential as an efficient adsorbent for removing Cu²⁺ ions from untreated natural water sources.