Concepedia

Formal allylic C(sp<sup>3</sup>)–H alkylation of α-alkylstyrenes by rearrangement of intermediate alkenyl sulfonium salts

Zeyu Shao, Junqi Zhou, Ziyu Wang, Biao Liu, Liang‐Hua Zou, Cheng Wang, Jian Wen

Organic Chemistry Frontiers · 2023 · 20 citations · 38 references

DOI

Concepts

Abstract

Allylic C(sp 3 )–H alkylation of α-alkylstyryl sulfonium salts based on [2,3]-sigmatropic rearrangement strategies has been developed. This protocol could allow facile access to allylated carbon quaternary centers in moderate to good yields.

References

38

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