Engineering S-scheme CuO/ZnO heterojunctions sonochemically for eradicating RhB dye from wastewater under solar radiation

Abstract

In this research, S-scheme heterojunctions composed of different concentrations of CuO and ZnO nanoparticles are fabricated for eradicating rhodamine B dye under solar radiation. ZnO nanoparticles are designed through a facile sol-gel route employing Triton X-100. Spherical CuO nanoparticles of 15.2 nm and 1.5 eV band gap energy are deposited on ZnO nanoparticles in an ultrasonic bath of 300 W intensity. The physicochemical performance of the photocatalyst is explored by HRTEM, SAED, BET, XRD, DRS and PL. The <i>in situ</i> homogeneous growth of spherical CuO nanoparticles on ZnO active centers shifts the photocatalytic response to the deep visible region and enhances the efficiency of charge carrier separation and transportation. Among all heterojunctions, ZnCu10 containing 10 wt% CuO displays the best photocatalytic rate for expelling 93% of RhB dye within 240 min, which is twenty-fold higher than that of pristine ZnO and CuO. Reactive oxygen species are the predominant species in degrading the dye pollutant on the heterojunction surface, as shown from scrubber trapping experiments and PL spectrum of terephthalic acid. Coupling ZnO as an oxidative photocatalyst and CuO as a reductive photocatalyst generates an efficient S-scheme heterojunction with strong redox power in destructing various organic pollutants.