Concepedia

Phosphonium ylide/organoaluminum-based Lewis pairs for the highly efficient living/controlled polymerization of alkyl (meth)acrylates

Zhikang Chen, Wuchao Zhao, Conglei Liu, Liuying Jiang, Gang Fu, Yuetao Zhang, Hongping Zhu

Polymer Chemistry · 2023 · 10 citations · 53 references

DOI

Concepts

Abstract

The Ph 3 PCHMe/AlMe(BHT) 2 initiator system efficiently induces the living/controlled polymerizations covering MMA, EMA, BnMA, n BuMA, n BA, and EHA monomers.

References

53

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, , +12

Ylide-Initiated Michael Addition−Cyclization Reactions beyond Cyclopropanes

Xiu‐Li Sun, Yong Tang · Accounts of Chemical Research · 2008 · 409 citations

, , +15

Alane‐Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High‐Molecular‐Weight Polymers

Yuetao Zhang, Garret M. Miyake, Eugene Y.‐X. Chen · Angewandte Chemie International Edition · 2010 · 292 citations

, , +13

Phosphorus Ylides in the Coordination Sphere of Transition Metals: An Inventory

Hubert Schmidbaur · Angewandte Chemie International Edition in English · 1983 · 273 citations

, , +10

Lewis acidity of tris(pentafluorophenyl)borane: crystal and molecular structure of B(C6F5)3·OPEt3

Michael A. Beckett, D.S. Brassington, Simon J. Coles et al. · Inorganic Chemistry Communications · 2000 · 216 citations

, , +14