Effects of Electrostatic Force and Network Structure on the Stability of Proton-Exchange Membrane Fuel Cell Catalyst Ink

Abstract

The stability of the catalyst slurry of a proton-exchange membrane fuel cell (PEMFC) is of great significance to its large-scale production and commercialization. In this study, three kinds of slurries with different stabilities were prepared using different probe ultrasonic powers. The influence of electrostatic force and network structure on slurry stability was also studied. In addition, the catalyst layer (CL) and membrane electrode assembly (MEA) were further tested to determine the relationship between slurry stability, CL, and MEA performance. The results showed that the slurry prepared with 600 W dispersion power had the least agglomeration on day 12, which is due to the clusters in the slurry having the smallest average particle size and the largest surface area, thereby allowing them to absorb the most Nafion and have the largest electrostatic force to inhibit agglomeration. However, the slurry with 1200 W dispersion power had the least sedimentation after 9.4 days because the strength of the network structure in the slurry strengthened the most, resulting in a significant increase in viscosity and inhibition of sedimentation. Electrochemical tests showed that the MEA gradually exhibited worse electrical performance and higher impedance due to the agglomeration of catalyst particles caused by the standing process. Altogether, this study provides insights to better understand and regulate the stability of catalyst slurries.