Concepedia

Double-resonance<sup>17</sup>O NMR experiments reveal unique configurational information for surface organometallic complexes

Frédéric A. Perras, Alejandra Arroyave, Scott A. Southern, Jessica V. Lamb, Yuting Li, Anne M. LaPointe, Massimiliano Delferro

Chemical Communications · 2023 · 10 citations · 40 references

DOIFull text

Open access

Concepts

Abstract

17 O-Labeling supports enables the determination of the 3D configuration of surface organometallic complexes. The procedure also allows for probing of the metal's chemical environment through 2D experiments involving the metal-bound oxygen.

References

40

Accurate First Principles Prediction of <sup>17</sup>O NMR Parameters in SiO<sub>2</sub>:  Assignment of the Zeolite Ferrierite Spectrum

Mickaël Profeta, Francesco Mauri, Chris J. Pickard · Journal of the American Chemical Society · 2002 · 422 citations

, , +17

Catalytic Cleavage of the C-H and C-C Bonds of Alkanes by Surface Organometallic Chemistry: An EXAFS and IR Characterization of a Zr-H Catalyst

Judith M. Corker, Frédéric Lefebvre, Christine Lécuyer et al. · Science · 1996 · 256 citations

, , +14

Realistic Models of Hydroxylated Amorphous Silica Surfaces and MCM‐41 Mesoporous Material Simulated by Large‐scale Periodic B3LYP Calculations

Piero Ugliengo, Mariona Sodupe, Federico Musso et al. · Advanced Materials · 2008 · 237 citations

, , +14

Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes

Zheng Huang, Maurice Brookhart, Alan S. Goldman et al. · Advanced Synthesis & Catalysis · 2009 · 136 citations

, , +17

Measuring multiple carbon–nitrogen distances in natural abundant solids using R-RESPDOR NMR

Zhehong Gan · Chemical Communications · 2006 · 113 citations

, , +7