Aligned Metal–Organic Framework Nanoplates in Mixed‐Matrix Membranes for Highly Selective CO₂/CH₄ Separation

Abstract

Abstract 2D metal–organic frameworks are attractive filler in mixed matrix membranes (MMMs) due to the high aspect ratio and contact opportunity at the filler–polymer interface. However, their alignment in polymer matrix remains a challenge to fully play their functions. Herein, to our best knowledge, for the first time, the facile synthesis of KAUST‐7‐NH 2 (KAUST, King University of Science and Technology) nanoplate is reported with 1D channels with an aspect ratio greater than 30. The nanoplates are incorporated and aligned in the 4,4′‐(hexafluoroisopropylidene) diphthalic anhydride‐2,4‐diaminomesitylene (6FDA‐DAM) polymer matrix under the shear force with a filler loading up to 50 wt%. The large difference in adsorption abilities between CO 2 and CH 4 from the (001)‐oriented KAUST‐7‐NH 2 nanoplate‐based MMMs and the favorable interaction at the filler–polymer interface contribute to the excellent CO 2 /CH 4 separation performance. The resultant membranes show CO 2 /CH 4 selectivity with 66.2% enhancement (surpassed 2008 Robeson upper bound), antiplasticization up to 17 bar, and long‐term stability up to 240 h indicating its good potential for natural gas treatment.