Concepedia

β-Trifluorosulfinylesters: tuneable reagents for switchable trifluoromethylsulfinylation and C–H trifluoromethylthiolation

Wen Liu, Yan Zhang, Shuya Xing, Huilin Lan, Xinrui Chen, Ying Bai, Xinxin Shao

Organic Chemistry Frontiers · 2023 · 16 citations · 32 references

DOI

Concepts

Abstract

β-Trifluorosulfinylesters, a family of novel reagents from commercially available starting materials for direct trifluoromethylthiolation and trifluoromethylsulfinylation were developed.

References

32

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Power-variable electrophilic trifluoromethylating agents. S-, Se-, and Te-(trifluoromethyl)dibenzothio-, -seleno-, and -tellurophenium salt system

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Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation

Xinxin Shao, Chunfa Xu, Long Lü et al. · Accounts of Chemical Research · 2015 · 401 citations

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

Fabien Toulgoat, Sébastien Alazet, Thierry Billard · European Journal of Organic Chemistry · 2014 · 401 citations

, , +9