Shortwave Ultraviolet Persistent Luminescence of Sr2MgSi2O7: Pr3+

Abstract

Currently, extensive research activities are devoted to developing persistent phosphors which extend beyond the visible range. In some emerging applications, long-lasting emission of high-energy photons is required; however, suitable materials for the shortwave ultraviolet (UV-C) band are extremely limited. This study reports a novel Sr₂MgSi₂O₇ phosphor doped with Pr³⁺ ions, which exhibits UV-C persistent luminescence with maximum intensity at 243 nm. The solubility of Pr³⁺ in the matrix is analysed by X-ray diffraction (XRD) and optimal activator concentration is determined. Optical and structural properties are characterised by photoluminescence (PL), thermally stimulated luminescence (TSL) and electron paramagnetic resonance (EPR) spectroscopy techniques. The obtained results expand the class of UV-C persistent phosphors and provide novel insights into the mechanisms of persistent luminescence.