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Synthesis and characterization of cobalt(iii) complexes containing 2-pyridinecarboxamide ligands and their application in catalytic oxidation of ethylbenzene with dioxygenElectronic supplementary information (ESI) available: full experimental and spectroscopic data for all compounds. See http://www.rsc.org/suppdata/cc/b3/b301963b/
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2003
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Engineering2-Pyridinecarboxamide LigandsCatalytic OxidationOrganic ChemistryChemistryInorganic CompoundChemical EngineeringOrganometallic CatalysisDioxygenelectronic Supplementary InformationMaterials ScienceInorganic ChemistryExcellent SelectivitiesCatalysisInorganic SynthesisCatalytic SynthesisOxygen Reduction ReactionCoordination ComplexSingle-atom CatalystNovel CobaltMolecular ComplexHigh Catalytic Activities
Four novel cobalt(III) complexes were found to have high catalytic activities and excellent selectivities in the oxidation of ethylbenzene to acetophenone using O2 as oxidant without need of solvent.