Enhanced Adsorption and Evaluation of Tetracycline Removal in an Aquatic System by Modified Silica Nanotubes

Abstract

adsorption-desorption isotherms. The later analysis suggested that the 3-APTES@MSNT nanoadsorbent has abundant surface functional groups, effective pore size distribution, a larger pore volume, and a relatively higher surface area. Furthermore, the influence of key adsorption parameters, including ambient temperature, ionic strength, initial TC concentration, contact time, initial pH, coexisting ions, and adsorbent dosage, had also been investigated. The 3-APTES@MSNT nanoadsorbent's ability to adsorb the TC molecules was found to be more compatible with Langmuir isothermal and pseudo-second-order kinetic models. Moreover, research on temperature profiles pointed to the process' endothermic character. In combination with the characterization findings, it was logically concluded that the 3-APTES@MSNT nanoadsorbent's primary adsorption processes involved interaction, electrostatic interaction, hydrogen bonding interaction, and the pore-fling effect. The synthesized 3-APTES@MSNT nanoadsorbent has an interestingly high recyclability of >84.6 percent up to the fifth cycle. The 3-APTES@MSNT nanoadsorbent, therefore, showed promise for TC removal and environmental cleanup.