1c:I[419806,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/30036bedc5269936.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/cd5e572bc3e4eb92.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/d4ac9dcf27f6ff52.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 1d:T434,Abstract A one‐pot reaction between Cu(BF 4 ) 2 · x H 2 O and 4‐mercaptobenzoic acid in acetone or methanol gives rise to the formation of lamellar microcrystals of two Cu(I)‐thiophenolate‐based coordination polymers (CPs) with the formulas [CuCT] n ( 1 ) (CT = 4‐carboxy‐thiophenolate) and [CuMCT] n ( 2 ) (MCT = 4‐methoxycarbonyl‐thiophenolate). Both 1 and 2 show a reversible luminescent thermochromic behavior upon cooling, changing their color from pale yellow to green to orange in the case of 1 , and from pale orange to green in the case of 2 . It is shown that the lamellar character of these crystals, which exhibit micrometer lateral dimensions and sub‐micrometer/nanometer thicknesses, allows processing them with an organic polymer such as polyvinylidene difluoride (PVDF) to form thermochromic 1 @PVDF and 2 @PVDF thin films. These thermal stimuli‐responsive thin films are freestanding, free of macroscopic defects, and robust under mechanical bending stress, opening up the possibility to use them in, for example, 2D imaging sensor films.1e:T501,One-pot reactions between CuI and methyl or methyl 2-amino-isonicotinate give rise to the formation of two coordination polymers (CPs) based on double zig-zag Cu₂I₂ chains. The presence of a NH₂ group in the isonicotinate ligand produces different supramolecular interactions affecting the Cu-Cu distances and symmetry of the Cu₂I₂ chains. These structural variations significantly modulate their physical properties. Thus, both CPs are semiconductors and also show reversible thermo/mechanoluminescence. X-ray diffraction studies carried out under different temperature and pressure conditions in combination with theoretical calculations have been used to rationalize the multi-stimuli-responsive properties. Importantly, a bottom-up procedure based on fast precipitation leads to nanofibers of both CPs. The dimensions of these nanofibres enable the preparation of thermo/mechanochromic film composites with polyvinylidene difluoride. These films are tens of nanometers in thickness while being centimeters in length, representing smaller thicknesses so far reported for thin-film composites. This nanomaterial integration of CPs could represent a source of alternative nanomaterials for opto-electronic device fabrication.1f:T481,Stretchable, mechanically stable films with thermally stable dual emission peaked in the blue and orange spectral range are fabricated by condensation and aging of carboxylated polyurethane in the presence of on-purpose aggregated copper nanoclusters. The aggregation of copper clusters leads to the enhancement of their emission in the orange, while polyurethane matrix contributes with the blue emission band, with an overall photoluminescence quantum yield of the films as high as 18%. Composite Cu nanoclusters/polyurethane films are sufficiently transparent over the visible spectral range and are absorbing in the UV range; more than 90% of their emission intensity is preserved after 10 times of cycle of stretch and recovery, as well as aging of up to 10 h at 90 °C, making them useful for optoelectronic devices. Remote white light-emitting devices (LEDs) have been fabricated by placing a down-conversion layer of composite Cu nanoclusters/polyurethane film separated through a silicone resin spacer from the UV LED chip, with Commission Internationale de l'Eclairage color coordinates of (0.34, 0.29), and a high color

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