In Situ Growth of Cs₃Bi₂Br₉ Quantum Dots on Bi-MOF Nanosheets via Cosharing Bismuth Atoms for CO₂ Capture and Photocatalytic Reduction

Abstract

Given the global warming caused by excess CO₂ accumulation in the atmosphere, it is essential to reduce CO₂ by capturing and converting it to chemical feedstock using solar energy. Herein, a novel Cs₃Bi₂Br₉/bismuth-based metal-organic framework (Bi-MOF) composite was prepared via an in situ growth strategy of Cs₃Bi₂Br₉ quantum dots (QDs) on the surface of Bi-MOF nanosheets through coshared bismuth atoms. The prepared Cs₃Bi₂Br₉/Bi-MOF exhibits bifunctional merits for both the high capture and effective conversion of CO₂, among which the optimized 3Cs₃Bi₂Br₉/Bi-MOF sample shows a CO₂-CO conversion yield as high as 572.24 μmol g^-1 h^-1 under the irradiation of a 300 W Xe lamp. In addition, the composite shows good stability after five recycles in humid air, and the CO₂ photoreduction efficiency does not decrease significantly. The mechanistic investigation uncovers that the intimate atomic-level contact between Cs₃Bi₂Br₉ and Bi-MOF via the coshared atoms not only improves the dispersion of Cs₃Bi₂Br₉ QDs over Bi-MOF nanosheets but also accelerates interfacial charge transfer by forming a strong bonding linkage, which endows it with the best performance of CO₂ photoreduction. Our new finding of bismuth-based metal-organic framework/lead-free halide perovskite by cosharing atoms opens a new avenue for a novel preparation strategy of the heterojunction with atomic-level contact and potential applications in capture and photocatalytic conversion of CO₂.