Synergistically Accelerating Adsorption‐Electrocataysis of Sulfur Species via Interfacial Built‐In Electric Field of SnS₂‐MXene Mott–Schottky Heterojunction in Li‐S Batteries

Abstract

Developing efficient heterojunction electrocatalysts and uncovering their atomic-level interfacial mechanism in promoting sulfur-species adsorption-electrocatalysis are interesting yet challenging in lithium-sulfur batteries (LSBs). Here, multifunctional SnS₂ -MXene Mott-Schottky heterojunctions with interfacial built-in electric field (BIEF) are developed, as a model to decipher their BIEF effect for accelerating synergistic adsorption-electrocatalysis of bidirectional sulfur conversion. Theoretical and experimental analysis confirm that because Ti atoms in MXene easily lost electrons, whereas S atoms in SnS₂ easily gain electrons, and under Mott-Schottky influence, SnS₂ -MXene heterojunction forms the spontaneous BIEF, leading to the electronic flow from MXene to SnS₂ , so SnS₂ surface easily bonds with more lithium polysulfides. Moreover, the hetero-interface quickly propels abundant Li⁺ /electron transfer, so greatly lowering Li₂ S nucleation/decomposition barrier, promoting bidirectional sulfur conversion. Therefore, S/SnS₂ -MXene cathode displays a high reversible capacity (1,188.5 mAh g^-1 at 0.2 C) and a stable long-life span with 500 cycles (≈82.7% retention at 1.0 C). Importantly, the thick sulfur cathode (sulfur loading: 8.0 mg cm^-2 ) presents a large areal capacity of 7.35 mAh cm^-2 at lean electrolyte of 5.0 µL mg_s ^-1 . This work verifies the substantive mechanism that how BIEF optimizes the catalytic performance of heterojunctions and provides an effective strategy for deigning efficient bidirectional Li-S catalysts in LSBs.