Low-Temperature Synthesis of Cu-Doped Anatase TiO2 Nanostructures via Liquid Phase Deposition Method for Enhanced Photocatalysis

Abstract

Titanium dioxide (TiO₂) photocatalysis can harness the energy from sunlight, providing a solution to many green- and energy-related problems. In this study, we aimed to produce Cu doped TiO₂ (Cu-TiO₂) structures at a low temperature (~70 °C) under atmospheric pressure based on liquid phase deposition. The products prepared with Cu nitrate exhibited anatase-phase TiO₂ with the presence of Cu, and the particles showed a waxberry-like structure. Changing the Cu nitrate concentration allowed control of the atomic concentration; we confirmed ~1.3 atm.% of Cu ions in the product when we applied 10 mM in the precursor solution. By doping Cu, the light absorption edge shifted to 440 nm (~2.9 eV), and we proved the photocatalytic reaction through action spectral measurement. We observed the decomposition of acetaldehyde into CO₂ on Cu-TiO₂ photocatalysts, which produced optimized improvements in photocatalytic activity at Cu dopant levels between 0.2 and 0.4 atm.%. This study demonstrates that the liquid phase deposition technique can be used for doping metallic ions into TiO₂, which shows promise for preparing novel and unique nanomaterials as visible light photocatalysts.