Concepedia

Photocatalyst-free, metal-free, visible light-induced thiolation/pyridylation of styrenes using an electron donor–acceptor complex as a bifunctional reagent

Jiaxuan Shen, Jincan Li, Meijun Chen, Yimin Chen

Organic Chemistry Frontiers · 2023 · 47 citations · 69 references

DOI

Concepts

Abstract

Visible light-induced intermolecular thiolation/pyridylation of styrenes using a thiolate-based EDA complex as a bifunctional reagent under mild conditions free of a photocatalyst, metal or external redox agent is reported.

References

69

Photoredox Catalysis in Organic Chemistry

Megan H. Shaw, Jack Twilton, David W. C. MacMillan · The Journal of Organic Chemistry · 2016 · 3.1K citations · Full text

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Synthetic Methods Driven by the Photoactivity of Electron Donor–Acceptor Complexes

Giacomo E. M. Crisenza, Daniele Mazzarella, Paolo Melchiorre · Journal of the American Chemical Society · 2020 · 1.2K citations · Full text

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Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

Andrew McNally, Christopher K. Prier, David W. C. MacMillan · Science · 2011 · 1K citations

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Free‐Radical‐Based, Specific Desulfurization of Cysteine: A Powerful Advance in the Synthesis of Polypeptides and Glycopolypeptides

Qian Wan, Samuel J. Danishefsky · Angewandte Chemie International Edition · 2007 · 864 citations

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Organic Synthesis Enabled by Light-Irradiation of EDA Complexes: Theoretical Background and Synthetic Applications

Carolina G. S. Lima, Thiago M. Lima, M.T. Duarte et al. · ACS Catalysis · 2016 · 727 citations

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