Selective Removal of Hexavalent Chromium by Novel Nitrogen and Sulfur Containing Cellulose Composite: Role of Counter Anions

Abstract

Exploiting an adsorbent with superb selectivity is of utmost importance for the remediation of Cr (VI)-laden wastewater. In this work, a novel nitrogen and sulfur functionalized 3D macroporous cellulose material (MPS) was prepared by homogeneous cross-link cellulose and polyvinylimidazole, followed by ion exchange with MoS₄^2-. MPS exhibited high removal efficiency at a broad pH range (1.0-8.0) and large adsorption capacity (379.78 mg/g) toward Cr (VI). Particularly, outstanding selectivity with an enormous partition coefficient (1.01 × 10⁷ mL/g) was achieved on MPS. Replacing MoS₄^2- with Cl^- and MoO₄^2- led to a sharp decline in adsorption selectivity, demonstrating that MoS₄^2- contributed substantially to the selectivity. Results of FTIR, XPS, and apparent kinetic analysis revealed that Cr (VI) was first pre-enriched on the MPS surface via electrostatic and dispersion forces, and then reacted with MoS₄^2- to generate Cr (III), which deposited on MPS by forming Cr(OH)₃ and chromium(III) sulfide. This study provides a new idea for designing adsorbents with a superior selectivity for removing Cr (VI) from sewage.