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Fast divalent conduction in MB<sub>12</sub>H<sub>12</sub>·12H<sub>2</sub>O (M = Zn, Mg) complex hydrides: effects of rapid crystal water exchange and application for solid-state electrolytes
18
Citations
81
References
2022
Year
Crystal StructureEngineeringElectrode-electrolyte InterfaceChemistryWater MoleculesFast Divalent ConductionMb 12Electrochemical InterfaceBiophysicsMaterials ScienceSolid-state IonicPhysical ChemistryHydrogenComplex HydridesElectrochemistrySolid-state ElectrolytesIonic ConductorHydrogen BondHydrogen-bonded Liquid
Water molecules are exchanged in the crystal structure, which imparts a high divalent conductivity to hydrated complex hydrides. MB 12 H 12 ·12H 2 O (M = Zn or Mg) exhibits exceptional conductivities higher than those of less-hydrated complex hydrides.
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