Concepedia

How long are Ga⇆Ga double bonds and Ga–Ga single bonds in dicationic gallium dimers?

Antoine Barthélemy, Harald Scherer, Hanna Weller, Ingo Krossing

Chemical Communications · 2022 · 27 citations · 41 references

DOIFull text

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Concepts

Abstract

We herein present the structures of two novel dicationic gallium dimers, a digallane and a digallene, as well as a detailed bonding analysis of the highly unusual bonding situations.

References

41

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How Short is a -Ga⋮Ga- Triple Bond? Synthesis and Molecular Structure of Na<sub>2</sub>[Mes*<sub>2</sub>C<sub>6</sub>H<sub>3</sub>-Ga⋮Ga-C<sub>6</sub>H<sub>3</sub>Mes*<sub>2</sub>] (Mes* = 2,4,6-<i>i</i>-Pr<sub>3</sub>C<sub>6</sub>H<sub>2</sub>):  The First Gallyne

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, , +7