Three-Dimensional Assemblies of Edge-Enriched WSe₂ Nanoflowers for Selectively Detecting Ammonia or Nitrogen Dioxide

Abstract

Herein, we present, for the first time, a chemoresistive-type gas sensor composed of two-dimensional WSe₂, fabricated by a simple selenization of tungsten trioxide (WO₃) nanowires at atmospheric pressure. The morphological, structural, and chemical composition investigation shows the growth of vertically oriented three-dimensional (3D) assemblies of edge-enriched WSe₂ nanoplatelets arrayed in a nanoflower shape. The gas sensing properties of flowered nanoplatelets (2H-WSe₂) are investigated thoroughly toward specific gases (NH₃ and NO₂) at different operating temperatures. The integration of 3D WSe₂ with unique structural arrangements resulted in exceptional gas sensing characteristics with dual selectivity toward NH₃ and NO₂ gases. Selectivity can be tuned by selecting its operating temperature (150 °C for NH₃ and 100 °C for NO₂). For instance, the sensor has shown stable and reproducible responses (24.5%) toward 40 ppm NH₃ vapor detection with an experimental LoD < 2 ppm at moderate temperatures. The gas detecting capabilities for CO, H₂, C₆H₆, and NO₂ were also investigated to better comprehend the selectivity of the nanoflower sensor. Sensors showed repeatable responses with high sensitivity to NO₂ molecules at a substantially lower operating temperature (100 °C) (even at room temperature) and LoD < 0.1 ppm. However, the gas sensing properties reveal high selectivity toward NH₃ gas at moderate operating temperatures. Moreover, the sensor demonstrated high resilience against ambient humidity (Rh = 50%), demonstrating its remarkable stability toward NH₃ gas detection. Considering the detection of NO₂ in a humid ambient atmosphere, there was a modest increase in the sensor response (5.5%). Furthermore, four-month long-term stability assessments were also taken toward NH₃ gas detection, and sensors showed excellent response stability. Therefore, this study highlights the practical application of the 2H variant of WSe₂ nanoflower gas sensors for NH₃ vapor detection.