International Journal of Molecular Sciences · 2022 · 13 citations · 51 references
Natural SciencesMaterials EngineeringMaterials ScienceCatalysisNanomaterialsNanotechnologyCatalyst CharacterizationCatalyst SynthesisCatalytic MaterialsNanoporous MaterialsSupported CatalystsSurface CatalysisCatalytic NanomaterialsDehydrogenationMesoporous NanomaterialsMesoporous Silica NanomaterialsMesoporous Silica NanoparticlesNanoparticle CatalystsNanostructured CatalystsPropane Conversion
PtSn catalysts were synthesized by incipient-wetness impregnation using a dendritic mesoporous silica nanoparticle support. The catalysts were characterized by XRD, N2 adsorption–desorption, TEM, XPS and Raman, and their catalytic performance for propane dehydrogenation was tested. The influences of Pt/Sn ratios were investigated. Changing the Pt/Sn ratios influences the interaction between Pt and Sn. The catalyst with a Pt/Sn ratio of 1:2 possesses the highest interaction between Pt and Sn. The best catalytic performance was obtained for the Pt1Sn2/DMSN catalyst with an initial propane conversion of 34.9%. The good catalytic performance of this catalyst is ascribed to the small nanoparticle size of PtSn and the favorable chemical state and dispersion degree of Pt and Sn species.
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