Concepedia

Effect of intermolecular anionic interactions on spin crossover of two triple-stranded dinuclear Fe(<scp>ii</scp>) complexes showing above room temperature spin transition

S. Athira, Dibya Jyoti Mondal, Shraoshee Shome, Bijoy Dey, Sanjit Konar

Dalton Transactions · 2022 · 19 citations · 42 references

DOI

Concepts

Abstract

Two new Fe(ii)-based dinuclear triple helicates [Fe 2 L 3 ] 4+ , displaying near room temperature spin transition have been synthesized and the effect of intermolecular interactions and co-operativity between metal centers on the SCO has been studied.

References

42

Crystal structure refinement with<i>SHELXL</i>

George M. Sheldrick · Acta Crystallographica Section C Structural Chemistry · 2014 · 42.5K citations · Full text

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<i>OLEX2</i>: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov, Luc J. Bourhis, Richard J. Gildea et al. · Journal of Applied Crystallography · 2009 · 31.6K citations

, , +16

Thermal and Optical Switching of Iron(<scp>II</scp>) Complexes

Philipp Gütlich, Andreas Hauser, H. Spiering · Angewandte Chemie International Edition in English · 1994 · 2.1K citations

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Emerging trends in spin crossover (SCO) based functional materials and devices

Senthil Kumar Kuppusamy, Mario Ruben · Coordination Chemistry Reviews · 2017 · 818 citations

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Supramolecular Self-Assembly of M-IDA Complexes Involving Lone-Pair···π Interactions: Crystal Structures, Hirshfeld Surface Analysis, and DFT Calculations [H<sub>2</sub>IDA = iminodiacetic acid, M = Cu(II), Ni(II)]

Saikat Kumar Seth, Indranil Saha, Carolina Estarellas et al. · Crystal Growth & Design · 2011 · 342 citations

, , +16