ACS Applied Materials & Interfaces · 2022 · 48 citations · 49 references
EngineeringMaterials EngineeringMaterials ScienceCeramic MaterialsCeramicsMicrowave EngineeringDielectric CeramicsDielectric MaterialsDielectric PropertiesMicrowave AntennasMicrowave MaterialsMicrowave ResonatorsCeramic DielectricsDielectric Resonator Antenna DesignDielectric Resonator AntennasDielectric ResonatorsMicrowave Dielectric CeramicsMicrowave Dielectric PropertiesPhase Transitions In Dielectric CeramicsThermal Expansion
Vanadium(V)-substituted cerium niobate [Ce(Nb1–xVx)O4, CNVx] ceramics were prepared to explore their structure–microwave (MW) property relations and application in C-band dielectric resonator antennas (DRAs). X-ray diffraction and Raman spectroscopy revealed that CNVx (0.0 ≤ x ≤ 0.4) ceramics exhibited a ferroelastic phase transition at a critical content of V (xc = 0.3) from a monoclinic fergusonite structure to a tetragonal scheelite structure (TF–S), which decreased in temperature as a function of x according to thermal expansion analysis. Optimum microwave dielectric performance was obtained for CNV0.3 with permittivity (εr) of ∼16.81, microwave quality factor (Qf) of ∼41 300 GHz (at ∼8.7 GHz), and temperature coefficient of the resonant frequency (TCF) of ∼ –3.5 ppm/°C. εr is dominated by Ce–O phonon absorption in the microwave band; Qf is mainly determined by the porosity, grain size, and proximity of TF–S; and TCF is controlled by the structural distortions associated with TF–S. Terahertz (THz) (0.20–2.00 THz, εr ∼ 12.52 ± 0.70, and tan δ ∼ 0.39 ± 0.17) and infrared measurements are consistent, demonstrating that CNVx (0.0 ≤ x ≤ 0.4) ceramics are effective in the sub-millimeter as well as MW regime. A cylindrical DRA prototype antenna fabricated from CNV0.3 resonated at 7.02 GHz (|S11| = −28.8 dB), matching simulations, with >90% radiation efficiency and 3.34–5.93 dB gain.
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