<i>In situ</i>crafting of a 3D N-doped carbon/defect-rich V₂O_5−<i>x</i>·<i>n</i>H₂O nanosheet composite for high performance fibrous flexible Zn-ion batteries

Abstract

Aqueous fibrous batteries with tiny volume, light weight and stretchability have furthered wearable smart textile systems like biocompatible electronics for a more efficient use of electricity. Challenges still faced by fibrous batteries include not only the deficient actual capacity but the cyclability on the cathode side. Herein, an <i>in situ</i> anodic oxidation strategy is reported to prepare 3D N-doped/defect-rich V₂O_5-<i>x</i>·<i>n</i>H₂O nanosheets (DVOH@NC) as fibrous cathodes for aqueous zinc-ion batteries (AZIBs). Benefiting from the substantially abundant reaction sites, enhanced electrical conductivity, short electron/ion diffusion path and high mass loading, the newly designed DVOH@NC fibrous electrode delivers impressive capacity (711.9 mA h cm^-3 at 0.3 A cm^-3) and long-term durability (95.5% capacity retention after 3000 cycles), substantially outperforming previously reported fibrous vanadium-based cathodes. First-principles density functional theory (DFT) calculations further revealed that the oxygen vacancies can weaken the electrostatic interaction between Zn²⁺ and the host cathode accompanying the low Zn²⁺ diffusion energy barrier. To highlight the potential applications, a prototype wearable fiber-shaped AZIB (FAZIB) with remarkable flexibility and extraordinary weaving capability was demonstrated. More encouragingly, the resulting FAZIB could be charged with solar cells and power a pressure sensor. Thus, our work provides a promising strategy to rationally construct high-performance flexible vanadium-based cathodes for next-generation wearable AZIBs.