Concepedia

Manipulating the d-band centers of transition metal phosphides through dual metal doping towards robust overall water splitting

Yunqing Liu, Zuhao Zhang, Lu Zhang, Yuguo Xia, Haiqing Wang, Hong Liu, Shenguang Ge, Jinghua Yu

Journal of Materials Chemistry A · 2022 · 126 citations · 61 references

DOI

Concepts

Abstract

By modulating the d band center via dual metal doping, and thus optimizing the adsorption free energy change for intermediates, the as prepared Ni–Mn–FeP exhibits outstanding catalytic performance toward both the OER ( η 10 = 185 mV) and HER ( η 10 = 103 mV).

References

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Tailoring the d-Band Centers Endows (Ni<sub><i>x</i></sub>Fe<sub>1–<i>x</i></sub>)<sub>2</sub>P Nanosheets with Efficient Oxygen Evolution Catalysis

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