Synthesis and characterization of a bimetallic americium(<scp>iii</scp>) pyrithionate coordination complex

Zachary K. Huffman, Joseph M. Sperling, Cory J. Windorff, Brian N. Long, Lucas Cordova, Harry Ramanantoanina, Cristian Celis‐Barros, Thomas E. Albrecht‐Schmitt

Chemical Communications · 2022 · 17 citations · 33 references

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Abstract

O shows significant splitting in the fingerprint excitations. This is attributed to a unique ligand-field environment, where the Am-mpo bonds possess different bonding compared to the Nd(III) analog because of increasing covalent interactions.

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