Bulletin of the Chemical Society of Japan · 2022 · 12 citations · 27 references
Natural SciencesChemistryCatalysisCatalytic MechanismsPhotocatalysisPhotochemical SynthesisPhotochemistryRadical ReactionsReaction MechanismsAllylic FunctionalizationC - H Bond FunctionalizationChemoselective Bond CleavagePhotochemical Bond CleavagePhotochemical FunctionalizationRadical Mediated C - H FunctionalizationSelective Bond CleavageSite-selective Functionalization
Abstract Photocatalytic C(sp3)-H allylation, alkynylation, and imination using unsaturated benzenesulfonyl compounds were studied using decatungstate anion, W10O324−, as photocatalyst. In all these reactions, site-selective C(sp3)-H bond cleavage was successfully combined with the radical addition/β-scission sequence.
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Davide Ravelli, Maurizio Fagnoni, Takahide Fukuyama et al. · ACS Catalysis · 2017 · 519 citations · Full text
Photoinduced intermolecular hydrogen atom transfer reactions in organic synthesis
Hui Cao, Xinxin Tang, Haidi Tang et al. · Chem Catalysis · 2021 · 446 citations