Concepedia

Photocatalytic dehydrogenated etherification of 2-aryl benzylic alcohols

Zhihui Liang, Chao Liu, Jiajun Fan, Mingze Wang, Xuanyu Yan, Mingqiang Huang, Shunyou Cai

Green Chemistry · 2022 · 17 citations · 54 references

DOI

Concepts

Abstract

Here we describe an efficient and practical method for the conversion of 2-aryl benzylic alcohols into the corresponding chromenes with the synergistic interactions of 2-bromoanthraquinone, O 2 , n Bu 4 NBr and K 2 CO 3 under visible-light irradiation.

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Visible-Light-Induced Alkoxyl Radical Generation Enables Selective C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Bond Cleavage and Functionalizations

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