Green Synthesis of a CuO–ZnO Nanocomposite for Efficient Photodegradation of Methylene Blue and Reduction of 4-Nitrophenol

Abstract

CuO-ZnO nanocomposites (NCs) were synthesized using an aqueous extract of <i>Verbascum sinaiticum</i> Benth. (GH) plant. X-ray diffraction (XRD), spectroscopic, and microscopic methods were used to explore the crystallinity, optical properties, morphology, and other features of the CuO-ZnO samples. Furthermore, catalytic performances were investigated for methylene blue (MB) degradation and 4-nitrophenol (4-NP) reduction. According to the results, CuO-ZnO NCs with 20 wt % CuO showed enhanced photocatalytic activity against MB dye with a 0.017 min^-1 rate constant compared to 0.0027 min^-1 for ZnO nanoparticles (NPs). Similarly, a ratio constant of 5.925 min^-1 g^-1 4-NP reductions was achieved with CuO-ZnO NCs. The results signified enhanced performance of CuO-ZnO NCs relative to ZnO NPs. The enhancement could be due to the synergy between ZnO and CuO, resulting in improved absorption of visible light and reduced electron-hole (e^-/h⁺) recombination rate. In addition, variations in the CuO content affected the performance of the CuO-ZnO NCs. Thus, the CuO-ZnO NCs prepared using <i>V. sinaiticum</i> Benth. extract could make the material a desirable catalyst for the elimination of organic pollutants.