Ultra‐Low Concentration Electrolyte Enabling LiF‐Rich SEI and Dense Plating/Stripping Processes for Lithium Metal Batteries

Abstract

The interface structure of the electrode is closely related to the electrochemical performance of lithium-metal batteries (LMBs). In particular, a high-quality solid electrode interface (SEI) and uniform, dense lithium plating/stripping processes play a key role in achieving stable LMBs. Herein, a LiF-rich SEI and a uniform and dense plating/stripping process of the electrolyte by reducing the electrolyte concentration without changing the solvation structure, thereby avoiding the high cost and poor wetting properties of high-concentration electrolytes are achieved. The ultra-low concentration electrolyte with an unchanged Li⁺ solvation structure can restrain the inhomogeneous diffusion flux of Li⁺ , thereby achieving more uniform lithium deposition and stripping processes while maintaining a LiF-rich SEI. The LiIICu battery with this electrolyte exhibits enhanced cycling stability for 1000 cycles with a coulombic efficiency of 99% at 1 mA cm^-2 and 1 mAh cm^-2 . For the LiIILiFePO₄ pouch cell, the capacity retention values at 0.5 and 1 C are 98.6% and 91.4%, respectively. This study offers a new perspective for the commercial application of low-cost electrolytes with ultra-low concentrations and high concentration effects.